N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide

C131H132N22O5 — CID 158314818

IUPACN-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
SMILESCn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1c[nH]c3ccccc13)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccc(-c3ccccc3)cc1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1cccc(-c3ccccc3)c1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccccc1)C2.O=C(NCc1ccccc1)c1nn(-c2ccccc2)c2c1CN(Cc1c[nH]c3ccccc13)CC2
InChIInChI=1S/C29H27N5O.2C28H28N4O.C24H25N5O.C22H24N4O/c35-29(31-17-21-9-3-1-4-10-21)28-25-20-33(19-22-18-30-26-14-8-7-13-24(22)26)16-15-27(25)34(32-28)23-11-5-2-6-12-23;1-31-26-15-16-32(19-22-11-8-14-24(17-22)23-12-6-3-7-13-23)20-25(26)27(30-31)28(33)29-18-21-9-4-2-5-10-21;1-31-26-16-17-32(19-22-12-14-24(15-13-22)23-10-6-3-7-11-23)20-25(26)27(30-31)28(33)29-18-21-8-4-2-5-9-21;1-28-22-11-12-29(15-18-14-25-21-10-6-5-9-19(18)21)16-20(22)23(27-28)24(30)26-13-17-7-3-2-4-8-17;1-25-20-12-13-26(15-18-10-6-3-7-11-18)16-19(20)21(24-25)22(27)23-14-17-8-4-2-5-9-17/h1-14,18,30H,15-17,19-20H2,(H,31,35);2-14,17H,15-16,18-20H2,1H3,(H,29,33);2-15H,16-20H2,1H3,(H,29,33);2-10,14,25H,11-13,15-16H2,1H3,(H,26,30);2-11H,12-16H2,1H3,(H,23,27)
InChIKeyGODBWCUMHHZVLC-UHFFFAOYSA-N
MW2094.65 g/mol
LogP20.29
Rot. Bonds28

About N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide

N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide (PubChem CID 158314818) has the molecular formula C131H132N22O5 and a molecular weight of 2094.65 g/mol. Its IUPAC name is N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide.

Molecular Properties

Compound NameN-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
PubChem CID158314818
Molecular FormulaC131H132N22O5
Molecular Weight2094.65 g/mol
Exact Mass2093.08
IUPAC NameN-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
SMILESCn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1c[nH]c3ccccc13)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccc(-c3ccccc3)cc1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1cccc(-c3ccccc3)c1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccccc1)C2.O=C(NCc1ccccc1)c1nn(-c2ccccc2)c2c1CN(Cc1c[nH]c3ccccc13)CC2
InChIInChI=1S/C29H27N5O.2C28H28N4O.C24H25N5O.C22H24N4O/c35-29(31-17-21-9-3-1-4-10-21)28-25-20-33(19-22-18-30-26-14-8-7-13-24(22)26)16-15-27(25)34(32-28)23-11-5-2-6-12-23;1-31-26-15-16-32(19-22-11-8-14-24(17-22)23-12-6-3-7-13-23)20-25(26)27(30-31)28(33)29-18-21-9-4-2-5-10-21;1-31-26-16-17-32(19-22-12-14-24(15-13-22)23-10-6-3-7-11-23)20-25(26)27(30-31)28(33)29-18-21-8-4-2-5-9-21;1-28-22-11-12-29(15-18-14-25-21-10-6-5-9-19(18)21)16-20(22)23(27-28)24(30)26-13-17-7-3-2-4-8-17;1-25-20-12-13-26(15-18-10-6-3-7-11-18)16-19(20)21(24-25)22(27)23-14-17-8-4-2-5-9-17/h1-14,18,30H,15-17,19-20H2,(H,31,35);2-14,17H,15-16,18-20H2,1H3,(H,29,33);2-15H,16-20H2,1H3,(H,29,33);2-10,14,25H,11-13,15-16H2,1H3,(H,26,30);2-11H,12-16H2,1H3,(H,23,27)
InChIKeyGODBWCUMHHZVLC-UHFFFAOYSA-N
XLogP20.29
TPSA282.38 Ų
H-Bond Donors7
H-Bond Acceptors20
Rotatable Bonds28
Heavy Atoms158
Complexity—

Lipinski Rule of Five

4 violations

RuleValue
MW ≤ 5002094.65
LogP ≤ 520.29
H-Bond Donors ≤ 57
H-Bond Acceptors ≤ 1020

Analyze N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide with MolForge

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Related Compounds

5-(1~{h}-Indol-3-Ylmethyl)-1-Methyl-~{n}-(Naphthalen-1-Ylmethyl)-6,7-Dihydro-4~{h}-Pyrazolo[4,3-C]pyridine-3-Carboxamide
CID 118933302
N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
CID 26219647
1-isobutyl-5-[(2-methyl-1H-indol-3-yl)acetyl]-N-(3-pyridinylmethyl)-4,5,6,7-tetrahydro-1H-pyrazolo[4,3-c]pyridine-3-carboxamide
CID 26138987
4-[10,15,20-tris(1-methylpyridin-1-ium-4-yl)-21,23-dihydroporphyrin-5-yl]-N-[[3-[[[4-[10,15,20-tris(1-methylpyridin-1-ium-4-yl)-21,23-dihydroporphyrin-5-yl]benzoyl]amino]methyl]phenyl]methyl]benzamide hexaiodide
CID 45266210
4-[10,15,20-tris(1-methylpyridin-1-ium-4-yl)-21,23-dihydroporphyrin-5-yl]-N-[[4-[[[4-[10,15,20-tris(1-methylpyridin-1-ium-4-yl)-21,23-dihydroporphyrin-5-yl]benzoyl]amino]methyl]phenyl]methyl]benzamide hexaiodide
CID 45266211
N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
CID 118933235
5-(1H-indol-3-ylmethyl)-1-methyl-N-(naphthalen-2-ylmethyl)-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide
CID 118933269
1-[2-[4-fluoro-2-[[5-(1H-pyrrolo[3,2-c]pyridin-4-yl)-3-pyridinyl]carbamoyl]pyrrolidin-1-yl]-2-oxoethyl]-5-pyridazin-4-ylindazole-3-carboxamide
CID 124134626
N-[5-[3-[4-(4-fluorophenyl)-1H-indol-2-yl]-7-[2-fluoro-5-[2-[5-[5-(pyrrolidin-1-ylmethyl)-3-pyridinyl]-1H-pyrazolo[4,3-b]pyridin-3-yl]-1H-indol-4-yl]phenyl]-1H-pyrazolo[4,3-b]pyridin-5-yl]-3-pyridinyl]benzamide
CID 137087958
N-[5-[3-[4-(4-fluorophenyl)-1H-indol-2-yl]-7-[2-fluoro-5-[2-[5-[5-(pyrrolidin-1-ylmethyl)-3-pyridinyl]-1H-pyrazolo[3,4-c]pyridin-3-yl]-1H-indol-4-yl]phenyl]-1H-pyrazolo[3,4-c]pyridin-5-yl]-3-pyridinyl]benzamide
CID 137102862
1-[2-[2-[(5-cyclohexyl-6-methyl-4-oxo-1H-pyrrolo[3,2-c]pyridin-3-yl)carbamoyl]-4-fluoropyrrolidin-1-yl]-2-oxoethyl]-5-pyridazin-4-ylindazole-3-carboxamide
CID 137434829
5-(5-fluoro-3-pyridinyl)-1-[1-[[5-[(5-pyridin-3-yl-1H-indazole-3-carbonyl)amino]-2-pyridinyl]methyl]pyrrolidin-3-yl]-N-[6-(trifluoromethyl)-3-pyridinyl]indazole-3-carboxamide
CID 144555306

Frequently Asked Questions

What is the IUPAC name of N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide?
The IUPAC name of N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide (CID 158314818) is N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide.
What is the SMILES notation for N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide?
The canonical SMILES for N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide is Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1c[nH]c3ccccc13)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccc(-c3ccccc3)cc1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1cccc(-c3ccccc3)c1)C2.Cn1nc(C(=O)NCc2ccccc2)c2c1CCN(Cc1ccccc1)C2.O=C(NCc1ccccc1)c1nn(-c2ccccc2)c2c1CN(Cc1c[nH]c3ccccc13)CC2.
What is the InChIKey of N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide?
The InChIKey is GODBWCUMHHZVLC-UHFFFAOYSA-N. The full InChI is InChI=1S/C29H27N5O.2C28H28N4O.C24H25N5O.C22H24N4O/c35-29(31-17-21-9-3-1-4-10-21)28-25-20-33(19-22-18-30-26-14-8-7-13-24(22)26)16-15-27(25)34(32-28)23-11-5-2-6-12-23;1-31-26-15-16-32(19-22-11-8-14-24(17-22)23-12-6-3-7-13-23)20-25(26)27(30-31)28(33)29-18-21-9-4-2-5-10-21;1-31-26-16-17-32(19-22-12-14-24(15-13-22)23-10-6-3-7-11-23)20-25(26)27(30-31)28(33)29-18-21-8-4-2-5-9-21;1-28-22-11-12-29(15-18-14-25-21-10-6-5-9-19(18)21)16-20(22)23(27-28)24(30)26-13-17-7-3-2-4-8-17;1-25-20-12-13-26(15-18-10-6-3-7-11-18)16-19(20)21(24-25)22(27)23-14-17-8-4-2-5-9-17/h1-14,18,30H,15-17,19-20H2,(H,31,35);2-14,17H,15-16,18-20H2,1H3,(H,29,33);2-15H,16-20H2,1H3,(H,29,33);2-10,14,25H,11-13,15-16H2,1H3,(H,26,30);2-11H,12-16H2,1H3,(H,23,27).
What are the key properties of N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide?
N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide has a molecular weight of 2094.65 g/mol, XLogP of 20.29, 28 rotatable bonds, 7 hydrogen bond donors, and 20 hydrogen bond acceptors.
Where does this data come from?
All data for N-benzyl-5-(1H-indol-3-ylmethyl)-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-5-(1H-indol-3-ylmethyl)-1-phenyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(3-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N-benzyl-1-methyl-5-[(4-phenylphenyl)methyl]-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide;N,5-dibenzyl-1-methyl-6,7-dihydro-4H-pyrazolo[4,3-c]pyridine-3-carboxamide is sourced from PubChem (CID 158314818), the world's largest open chemistry database maintained by the National Library of Medicine (NIH).